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Reimagining liquid transportation fuels [electronic resource] : sunshine to petrol

Two of the most daunting problems facing humankind in the twenty-first century are energy security and climate change. This report summarizes work accomplished towards addressing these problems through the execution of a Grand Challenge LDRD project (FY09-11). The vision of Sunshine to Petrol is captured in one deceptively simple chemical equation: Solar Energy + xCO₂ + (x+1)H₂O → CₓH{sub 2x+2}(liquid fuel) + (1.5x+.5)O₂ Practical implementation of this equation may seem far-fetched, since it effectively describes the use of solar energy to reverse combustion. However, it is also representative of the photosynthetic processes responsible for much of life on earth and, as such, summarizes the biomass approach to fuels production. It is our contention that an alternative approach, one that is not limited by efficiency of photosynthesis and more directly leads to a liquid fuel, is desirable. The development of a process that efficiently, cost effectively, and sustainably reenergizes thermodynamically spent feedstocks to create reactive fuel intermediates would be an unparalleled achievement and is the key challenge that must be surmounted to solve the intertwined problems of accelerating energy demand and climate change. We proposed that the direct thermochemical conversion of CO₂ and H₂O to CO and H₂, which are the universal building blocks for synthetic fuels, serve as the basis for this revolutionary process. To realize this concept, we addressed complex chemical, materials science, and engineering problems associated with thermochemical heat engines and the crucial metal-oxide working-materials deployed therein. By project's end, we had demonstrated solar-driven conversion of CO₂ to CO, a key energetic synthetic fuel intermediate, at 1.7% efficiency.

Online OSTI

Liquid transport processes in polymeric materials : modeling and industrial applications

Liquid transportation fuels from coal and biomass : technological status, costs, and environmental impacts

"The transportation sector cannot continue on its current path: The volatility of oil prices threatens the U.S. economy, the large proportion of oil importation threatens U.S. energy security, and the massive contribution of greenhouse gases threatens the environment. The development of domestic sources of alternative transportation fuels with lower greenhouse emissions is now a national imperative. Coal and biomass are in abundant supply in the United States and can be converted to liquid fuels that can be combusted in existing and future vehicles. Their abundant supply makes them attractive candidates to provide non-oil-based liquid fuels to the U.S. transportation system. However, there are important questions about the economic viability, carbon impact, and technology status of these options. Liquid Transportation Fuels from Coal and Biomass provides a snapshot of the potential costs of liquid fuels from biomass by biochemical conversion and from biomass and coal by thermochemical conversion. Policy makers, investors, leaders in industry, the transportation sector, and others with a concern for the environment, economy, and energy security will look to this book as a roadmap to independence from foreign oil. With immediate action and sustained effort, alternative liquid fuels can be available in the 2020 time frame, if or when the nation needs them"--Page 4 of coverThe transportation sector cannot continue on its current path: The volatility of oil prices threatens the U.S. economy, the large proportion of oil importation threatens U.S. energy security, and the massive contribution of greenhouse gases threatens the environment. The development of domestic sources of alternative transportation fuels with lower greenhouse emissions is now a national imperative. Coal and biomass are in abundant supply in the United States and can be converted to liquid fuels that can be combusted in existing and future vehicles. Their abundant supply makes them attractive candidates to provide non-oil-based liquid fuels to the U.S. transportation system. However, there are important questions about the economic viability, carbon impact, and technology status of these options. Liquid Transportation Fuels from Coal and Biomass provides a snapshot of the potential costs of liquid fuels from biomass by biochemical conversion and from biomass and coal by thermochemical conversion. Policy makers, investors, leaders in industry, the transportation sector, and others with a concern for the environment, economy, and energy security will look to this book as a roadmap to independence from foreign oil. With immediate action and sustained effort, alternative liquid fuels can be available in the 2020 time frame, if or when the nation needs them.

Online EBSCO Academic Comprehensive Collection